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doi:10.1177/0194599818762383 Kent DT, Carden KA, Wang L, Lindsell CJ, Ishman SL

Living skin has blood circulation that clears delivered molecules at a rate the Franz cell does not capture, and a longer functional half-life of the peptide in tissue is implied but not directly measured

Although the reaction of PhSeBr and 1a generating the SeN intermediate INT1-Se is endothermic by 12.6 kcal mol 1 , INT1-Se may readily undergo a Se-centred [2,3]-sigmatropic rearrangement to generate an ortho -Se = N substituted dearomatized species ( INT2-Se ) via TS1-Se , with a barrier of 12.7 kcal mol 1

Such observations have also been seen in human liver cirrhosis [20]