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Much to our delight, however, the introduction of the electron-withdrawing substituent CF 3 (catalyst ( R )- 1d ) and C 2 F 5 (catalyst ( R )- 1e ), rather than the iodo-substituent of ( R )- 1c at the 3,3-position of the binaphthyl scaffold, resulted in a nearly complete conversion after the same reaction time, with excellent enantioselectivities (98% and 94% ee in entries 4 and 6, respectively)

Protein kinase A-anchoring (AKAP) domains in brefeldin A-inhibited guanine nucleotide-exchange protein 2 (BIG2)

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