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Dopamine-derived quinones (DA-Q) can undergo intramolecular cyclization and oxidation to form leukochrome, aminochrome, and finally, neuromelanin, a pigment involved in neuroinflammation and neurodegeneration (Zecca et al

However, the barrier for the regeneration of N -phenylthiophthalimide 4g (via TS SN2 ) is up to 32.3 kcal mol 1 , suggesting the turnover of 4g is difficult even under basic condition