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While the emergence of amyloids may have begun as early as LUCA [84], the existence of a proteostasis-defending heat shock response system that arose around the same time implies that this relationship is not only evolutionarily conserved but should also be robust and effective [154]

Antioxid Redox Signal 15:233270 Zaffagnini M, Bedhomme M, Marchand CH, Morisse S, Trost P, Lemaire SD (2012) Redox regulation in photosynthetic organisms: focus on glutathionylation

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(2018) Tesamorelin Falutz J, Allas S, Blot K, et al

It is also noteworthy that the k cat of the two enzymes also differ by 3-fold, something that we cannot explain using static structures and may involve distinctions in active site motion, as outlined elegantly for other enzyme systems 30