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[PubMed] [Google Scholar] 13.Hexsel D, Arellano I, Rendon M

B.BessedeA.GluchL.GuilleminG

For this plot, the C-H bond lengths were converted to changes in Pauling bond order, which allows one to find by inspection the extent to which the C-H bond is broken in the ground state for a given observed binding isotope effect

The lipid hydroperoxide (ROOH) is unstable in the presence of iron or other metal catalysts because ROOH will participate in a Fenton reaction leading to the formation of reactive alkoxy radicals