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The method is illustrated by one synthesis of thioglycolic acid: ClCH 2 CO 2 H + Na 2 S 2 O 3 Na[O 3 S 2 CH 2 CO 2 H] + NaCl Na[O 3 S 2 CH 2 CO 2 H] + H 2 O HSCH 2 CO 2 H + NaHSO 4 Organolithium compounds and Grignard reagents react with sulfur to give the thiolates, which are readily hydrolyzed: [27] RLi + S RSLi RSLi + HCl RSH + LiCl Phenols can be converted to the thiophenols via rearrangement of their O -aryl dialkylthiocarbamates

Veillez tenir le corps de l'ampoule d'une main, entre le pouce et l'index repli, avec la tte de l'ampoule buvable oriente vers le haut

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10.1016/j.bmcl.2013.09.071 54 LopezO