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This may be due to the fact, that homeostasis of redox metals is tightly controlled and free metals (e.g

But don't let its simple structure fool you

However, loss of GPX1 induced the expression of cyclooxygenase-2 and release of prostaglandins [119]

& Hamprecht, B

The redox cycling enzymes thioredoxin, thioredoxin reductase, sulfiredoxin, peroxiredoxin, GSH peroxidase, superoxide dismutase 1, and catalase, and several GSH S-transferases, which are the enzymes mediating the elimination of ROS, are all Nrf2 targets (242)