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In the M(Bpy) catalyses, catalytically active species are likely to be in the form of Bpy-monochelated M-complexes M(Bpy), but dynamic coordination equilibria per-turb the number of Bpy ligands on the M atom (Fig

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Metabolic reprogramming further exacerbates immunosuppression, such as the conversion of extracellular ATP to adenosine mediated by the CD39/CD73 axis, which not only inhibits CTL function but also promotes T cell exhaustion by activating the adenosine A2A receptor (ADORA2A) (207)