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The metabolites cyclic 3-hydroxy melatonin, N1-acetyl-N2-formyl-5-methoxykynuramine (AFMK), and N1-acetyl-5-methoxykynuramine (AMK), which can reduce free radicals, are formed when MLT reacts directly with free radicals, including hydroxyl (OH ), superoxide (O 2 ), and reactive nitrogen species, such as nitric oxide (NO ) The hypothesis that MLT has a multifunctional role as a mitochondrial antioxidant is supported by numerous investigations [116,117,118]

The NO-donors O2-(2,4-Dinitrophenyl)-1-[(4-ethoxycarbo-nyl)piperazin-1-yl]diazen-1-ium-1,2-diolate (JS-K), (Z)-1-[N-(2-Aminoethyl)-N-(2-ammonioethyl)amino]diazen-1-ium-1,2-diolate (DETA/NO) and the androgen dihydrotestosterone (DHT) were a products of Sigma Aldrich (Taufkirchen, Germany)

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[2] state contract of the Ministry of Science and Higher Education of the Russian Federation Genetic and epigenetic editing of tumor cells and microenvironment in order to block metastasis no