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Intramolecular reactions can gain considerable rate enhancement compared to intermolecular reactions due to several different reasons (14, 64): (i) In an intermolecular reaction, a wide distribution of rotamers exist and statistical factors (as well as concentration) determine the probability of the conformation that undergoes reaction

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Additionally, Vitamin C helps protect the skin from environmental damage, such as UV exposure and helps in reducing the appearance of dark spots

XLi and XLa edited and revised manuscript